Chemker 300 - Chemical Resistant Vacuum Pump

Availability of clean water is of concern due to pollution and diminishing supply pollution. However, purification is possible depending on the incorporated contaminants. Domestic wastewater contains dissolved organic matter and its remediation can be done by oxidation. The best oxidation can be achieved by electron transfer the same way metabolic processes occur. This study exploited the use of a film of iron (III) doped titanium dioxide applied on an electrode which was found to be effective. Natural light conditions generated electrons that migrated through the electrode leaving behind holes which oxidized the contaminants as the excess electrons were discharged at the cathode after passing through the casted proton exchange membrane (PEM) separating the two half cells of the prepared reactor. This electrochemical method has the advantage in that the organic pollutants are oxidized to carbon dioxide with no secondary pollutants and the inorganic pollutants into insoluble matter. The assembled cell was applied to purify both synthetic and real water samples of green leafy vegetable solution from the kitchen by clarification. The clarification process was monitored by UV-Vis using distilled water as a reference to compare the light that transmitted through a sample. It was observed that the electro-oxidation process took place showing a high potential 105 mV within the first 150 min followed by degradation at a high rate. The oxidation of the organic matter was confirmed by UV-Vis analysis as well as by cyclic voltametric analysis of iron released into the solution of the synthetic samples. The electro chemical treatment of the water was then applied to purify real water samples made from a sample of 4.5 g minced of green vegetables dispersed in one liter of water (4.5 g/l). The green leafy coloured solution was clarified after 154 h of continuous oxidation. The degradation process was confirmed to be independent of intermediates or other species present in solution as it was of first order reaction kinetics. The electrochemical oxidation of organic matter in water using iron (III) doped titanium dioxide coated graphite electrode has potential application on the purification of water.

Biocompatible smart interfaces play a crucial role in biomedical or tissue engineering applications, where their ability to actively change their conformation or physico-chemical properties permits finely tuning their surface attributes. Polyelectrolytes, such as acrylic acid, are a particular type of smart polymers that present pH responsiveness. This work aims to fabricate stable hydrogel films with reversible pH responsiveness that could spontaneously form wrinkled surface patterns. For this purpose, the photosensitive reaction mixtures were deposited via spin-coating over functionalized glasses. Following vacuum, UV, or either plasma treatments, it is possible to spontaneously form wrinkles, which could increase cell adherence. The pH responsiveness of the material was evaluated, observing an abrupt variation in the film thickness as a function of the environmental pH. Moreover, the presence of the carboxylic acid functional groups at the interface was evidenced by analyzing the adsorption/desorption capacity using methylene blue as a cationic dye model. The results demonstrated that increasing the acrylic acid in the microwrinkled hydrogel effectively improved the adsorption and release capacity and the ability of the carboxylic groups to establish ionic interactions with methylene blue. Finally, the role of the acrylic acid groups and the surface topography (smooth or wrinkled) on the final antibacterial properties were investigated, demonstrating their efficacy against both gram-positive and gram-negative bacteria model strains (E. coli and S. Aureus). According to our findings, microwrinkled hydrogels presented excellent antibacterial properties improving the results obtained for planar (smooth) hydrogels.

In this study, four new silicon-containing poly(ether-azomethine)s with linear structures were prepared using original silicon and biphenyl moiety-containing monomers: two diamines and two dialdehydes. The oligomeric natures of the samples were established by GPC analysis, which showed chains containing 3 to 5 repetitive units. The monomers and the oligomeric samples were structurally characterized by NMR and FT-IR spectroscopy. The solubilities of the samples in common organic solvents and their thermal behavior enable improvement of their industrial and technological processability. The optical band gaps of the oligomeric samples were estimated from optical measurements (UV-vis), and their electrical behavior in films was determined using the four-point method. The surface arrangements and morphological characteristics of the films were determined via atomic force microscopy measurements. The roughness, area increase percentage and layer stiffness of the films were also measured using this technique.